OPTIMUM CONTROL OF CATHOLIC REACTION OF TSIKLOALYUMINIROVANIYA OF OLEFINS AND ACETYLINUMS ON THE BASIS OF NUMERICAL MODEL OPERATION

Abstract


The catalytic reaction of a tsikloalyuminirovaniye of olefins and Acetylinums is considered, its kinetic model is constructed. The database of kinetic researches is designed and introduced. The mathematical description of reaction is made. Direct and inverse kinetic tasks are solved. The complex of programs for research of reactivity of olefinic and acetylene connections is developed. Computing experiment is made for the quantitative assessment of reactivity of a number of olefins and Acetylinums.

About the authors

Yu. S Lavrentyeva

Institute of petrochemistry and catalysis of the Russian Academy of Sciences

Email: uliyalavr@mail.ru

L. R Abzalilova

Institute of petrochemistry and catalysis of the Russian Academy of Sciences

Email: abzalilova.liya@gmail.com

I. M Gubaidulin

Institute of petrochemistry and catalysis of the Russian Academy of Sciences

Email: irekmars@mail.ru

References

  1. Механизм реакции циклоалюминирования алкенов триэтилалюминием в алюмациклопентанты, катализируемой Cp2ZrCl2 / А.В. Балаев, Л.В. Парфенова, С.В. Русаков, И.М. Губайдуллин, С.И. Спивак, Л.М. Халилов, У.М. Джемилев // ДАН. - 2001. - Т. 381, № 3.
  2. Kinetic Model of Olefins Hydrometallation by HAlBui2 and AlBui3 in the Presence Cp2ZrCl2 Catalyst / L.V. Parfenova, A.V. Balaev, I.M. Gubaidullin, L.R. Abzalilova, S.V. Pechatkina, L.M. Khalilov, S.I. Spivak, U.M. Dzhemilev // Int. J. Chem. Kinet. - 2007. - Vol. 39, № 6. - Р. 333-339.
  3. Multiple Mechanistic Pathways for Zirconium- Catalyzed Carboalumination of Alkynes. Requirements for Cyclic Carbometallation Processes Involving C-H Activation / E.I. Negishi, D.Y. Kondakov, D. Choueiri, K. Kasai, T. Takahashi // J. Amer. Chem. Soc. - 1996. - Vol. 118, № 40. - P. 9577-9588.
  4. Рамазанов И.Р., Кадикова Р.Н., Джемилев У.М. Катализируемое Cp2ZrCl2 циклоалюминирование ацетиленовых спиртов и пропаргиламинов под действием Et3Al // Изв. АН. Сер. Химия. - 2011. - № 1. - С. 96-102.
  5. Парфенова Л.В., Халилов Л.М., Джемилев У.М. Механизмы реакций алюминийорганических соединений с алкенами и алкинами, катализируемых комплексами циркония // Успехи химии. - 2012. - С. 524-548.
  6. Губайдуллин И.М., Спивак С.И. Информационно-аналитическая система обратных задач химической кинетики // Системы управления и информационные технологии. - 2008. - № 1.1(31). - С. 150-153.

Statistics

Views

Abstract - 49

PDF (Russian) - 25

Refbacks

  • There are currently no refbacks.

Copyright (c) 2014 Lavrentyeva Y.S., Abzalilova L.R., Gubaidulin I.M.

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies