IMPACT OF EQUAL-CHANNEL ANGULAR PRESSING ON MECHANICAL BEHAVIOR AND MICROSTRUCTURE OF MAGNESIUM ALLOYS

Abstract


Preparation of materials for hydrogen saturation as a primary treatment involves its refinement. This allows improving the kinetic parameters of sorption / desorption of hydrogen by increasing the pro- portion of the specific surface of the sample. The efficiency of particle size reduction depends on the mechanical characteristics of the material.We studied the mechanical properties of samples of magnesium and magnesium alloys AZ31 and ZK60 before and after deformation with equal channel angular pressing (ECAP). It is shown that results in deformation of the ECAP are: anisotropy of mechanical properties appearance as well as increased strength, yield strength and modulus decrease. The possible mechanisms for the implemen- tation of microplastic deformation were discussed. It was shown that the ECAP deformation creates the texture in material which lead to anisotropy of mechanical properties.It was found that in the investigated materials, severe plastic deformation, as for example ECAP, is carried out mainly by sliding along the basal planes, which is typical for crystals with hexago- nal close packing with the ratio of the lattice parameters close to ideal (c / a ~ 1.63). The second contri- bution (in magnitude and significance) on the deformation is twinning. Calculation texture formed during ECAP deformation showed that in alloys based on magnesium twinning implemented on the {10-12} plants in the direction of shear <-1011>. This one prevents the occurrence in the deformation process involving other slip systems, namely, sliding on prismatic and pyramidal planes of the crystal lattice.The analysis of the deformation behavior of magnesium and its alloys can be used as the basis for creation of the technology of materials with ultra fine structure for hydrogen storage based on the reversible hydrides.

About the authors

N E Skryabina

Perm State National Research University

Email: natskryabina@mail.ru

V N Aptukov

Perm State National Research University

Email: aptukov@psu.ru

P V Romanov

Perm State National Research University

Email: petr_rom@yahoo.com

D Fruchart

Institut Néel

Email: daniel.fruchart@neel.cnrs.fr

References

  1. Тарасов Б.П., Лотоцкий М.В., Яртысь В.А. Проблема хранения водорода и перспективы использования гидридов для аккумули-рования водорода // Рос. хим. журн. - 2006. - Т. 1, № 6. - C. 34-48.
  2. Формирование текстуры деформации в сплаве AZ31 под воздей-ствием равноканального углового прессования / Н.Е. Скрябина, Д. Фрушар, Г. Жирард, С. Мираглиа // Вестник Пермского университета. Физика. - 2010. - № 1. - С. 97-101.
  3. Valiev R.Z., Langdon T.G. Principles of equal channel angular press-ing as a processing tool for grain refinement // Prog. In Mater. Sci. - 2006. - Vol. 51. - P. 881-981.
  4. Equal Channel Angular Pressing (ECAP), a severe plastic deformation (SPD) technique to promote fast hydrogen absorption in mg alloys / G. Girard, D. Fruchart, S. Miraglia [et al.] // Metal Hydrogen Systems: Proc. Inter. Sympos. - Moscow, 2010. - P. 141.
  5. Пшеничников Ю.П. Выявление тонкой структуры кристаллов. - М.: Металлургия, 1974. - 528 с.
  6. Диаграммы состояния двойных металлических систем: справоч-ник: в 3 т. Т. 1 / под ред. Н.П. Лякишева. - М.: Машиностроение, 1996. - С. 167-170.
  7. Celotto S., Bastow T.J. Study Of Precipitation In Aged Binary Mg-Al And Ternary Mg-Al-Zn Alloys Using 27Al NMR Spectroscopy // Acta Materialia. - 2001. - Vol. 49. - P. 41-51.
  8. Microstructure and texture of twin-roll cast Mg-3Al-1Zn-0.2Mn magnesium alloy / N. Tang, M.P. Wang, H.F. Lou, Y.Y. Zhao, Z. Li // Materials Chemistry and Physics. - 2009. - Vol. 116. - P. 11-15.
  9. Braszczyńska-Malik K. N. Discontinuous and continuous precipitation in magnesi-um-aluminium type alloys // J. Alloys Comp. - 2009. - Vol. 477. - P. 870-876.
  10. Bhan S., Lal A. The Mg-Zn-Zr System (Magnesium-Zinc-Zirco¬nium) // Journal of Phase Equilibria. - 1993. - Vol. 14. - No. 5. - P. 634-637.
  11. Investigation on the Alloy Phases in As-aged ZK60 Magnesium Alloy / F. Pan, W. Wang, Y. Ma, R. Zuo, A. Tang, J. Zhang // Materials Sci-ence Forum. - 2005. - Vol. 488-489. - P. 181-184.
  12. Полухин П.И., Горелик С.С., Воронцов В.К. Физические основы пластической деформации. - М.: Металлургия, 1982. - 584 с.
  13. Hiura F. Latent Hardening in pure magnesium single crystals // Master of Science thesis. - Canada, 2010. - 116 р.
  14. Черняева Т.П., Грицина В.М. Характеристики ГПУ-металлов, определяющие их поведение при механическом, термическом и радиационном воздействии // Вопросы атомной науки и техники. - 2008. - Вып. 2. - С. 15-27.
  15. De-formation twinning in AZ31: Influence on strain hardening and texture evolution / M. Knezevic, A. Levinson, R. Harris, R.K. Mishra, R.D. Doherty, S.R. Kalidindi // Acta Mater. - 2010. - Vol. 58. - P. 6230-6242.
  16. Non-Schmid behaviour during secondary twinning in a polycrystalline magnesium alloy / M.R. Barnett, Z. Keshavarz, A.G. Beer, X. Ma // Acta Mater. - 2008. - Vol. 56. - P. 5-15.
  17. Скрябина Н.Е., Пинюгжанин В.М., Фрушар Д. Механизмы фор-мирования текстуры сплава AZ31 в процессе РКУП // Вестник Пермского университета. Физика. - 2011. - Вып. 2(17). - С. 79-86.

Statistics

Views

Abstract - 147

PDF (Russian) - 198

Cited-By


PlumX


Copyright (c) 2014 Skryabina N.E., Aptukov V.N., Romanov P.V., Fruchart D.

Creative Commons License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

This website uses cookies

You consent to our cookies if you continue to use our website.

About Cookies